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Comparisons of three nicotine dependence scales in a multiethnic sample of young adult menthol and non-menthol smokers 2015 Cancer Prevention and Control Program, University of Hawaii Cancer Center, University of Hawaii at Manoa, 701 Ilalo Street, Honolulu, HI 96813, USA. Electronic address: pfagan@cc.hawaii.edu.; Cancer Prevention and Control Program, University of Hawaii Can
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Drug and alcohol dependence
Periodical, Abbrev.
Drug Alcohol Depend.
Pub Date Free Form
1-Apr
Volume
149
Issue
Start Page
203
Other Pages
211
Notes
LR: 20160715; CI: Copyright (c) 2015; GR: K01 CA148789/CA/NCI NIH HHS/United States; GR: P30 CA071789/CA/NCI NIH HHS/United States; GR: R03 CA159909/CA/NCI NIH HHS/United States; GR: R21 CA180934/CA/NCI NIH HHS/United States; GR: U54 MD007584/MD/NIMHD NIH
Place of Publication
Ireland
ISSN/ISBN
1879-0046; 0376-8716
Accession Number
PMID: 25744873
Language
eng
SubFile
Comparative Study; Journal Article; Research Support, Non-U.S. Gov't; IM
DOI
10.1016/j.drugalcdep.2015.02.005 [doi]
Output Language
Unknown(0)
PMID
25744873
Abstract
BACKGROUND: Few studies have compared nicotine dependence among menthol and non-menthol cigarette smokers in a multiethnic sample of young adult daily cigarette smokers. This study examines differences in nicotine dependence among menthol and non-menthol daily smokers and the associations of nicotine dependence with quitting behaviors among Native Hawaiian, Filipino, and White cigarette smokers aged 18-35. METHODS: Craigslist.org, newspaper advertisements, and peer-to-peer referrals were used to recruit daily smokers (n = 186) into a lab-based study. Nicotine dependence was assessed using the Fagerstrom Test of Nicotine Dependence (FTND), the Nicotine Dependence Syndrome Scale (NDSS), and the brief Wisconsin Inventory for Smoking Dependence Motives (WISDM). Multiple regression analyses were used to examine differences in nicotine dependence between menthol and non-menthol smokers and the relationship between each nicotine dependence scale with self-efficacy to quit, quit attempt in the past 12 months, and number of attempts. RESULTS: Menthol smokers were more likely to report difficulty refraining from smoking in places where forbidden (p = .04) and had higher scores on social/environmental goads subscale of the WISDM (p = .0005). Two-way interaction models of the FTND and menthol status showed that menthol smokers with higher levels of dependence were more likely to have tried to quit smoking in the past 12 months (p = .02), but were less likely to have had multiple quit attempts (p = .01). CONCLUSIONS: Components of the FTND and WISDM distinguish levels of dependence between menthol and non-menthol smokers. Higher FTND scores were associated with having a quit attempt, but fewer quit attempts among menthol smokers.
Descriptors
Links
Book Title
Database
Publisher
Elsevier Ireland Ltd
Data Source
Authors
Fagan,P., Pohkrel,P., Herzog,T., Pagano,I., Vallone,D., Trinidad,D.R., Sakuma,K.L., Sterling,K., Fryer,C.S., Moolchan,E.
Original/Translated Title
URL
Date of Electronic
20150214
PMCID
PMC4865397
Editors
Monitoring Exposure to Ebola and Health of U.S. Military Personnel Deployed in Support of Ebola Control Efforts - Liberia, October 25, 2014-February 27, 2015 2015
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
MMWR.Morbidity and mortality weekly report
Periodical, Abbrev.
MMWR Morb.Mortal.Wkly.Rep.
Pub Date Free Form
3-Jul
Volume
64
Issue
25
Start Page
690
Other Pages
694
Notes
JID: 7802429; ppublish
Place of Publication
United States
ISSN/ISBN
1545-861X; 0149-2195
Accession Number
PMID: 26135589
Language
eng
SubFile
Journal Article; IM
DOI
mm6425a2 [pii]
Output Language
Unknown(0)
PMID
26135589
Abstract
In response to the unprecedented Ebola virus disease (Ebola) outbreak in West Africa, the U.S. government deployed approximately 2,500 military personnel to support the government of Liberia. Their primary missions were to construct Ebola treatment units (ETUs), train health care workers to staff ETUs, and provide laboratory testing capacity for Ebola. Service members were explicitly prohibited from engaging in activities that could result in close contact with an Ebola-infected patient or coming in contact with the remains of persons who had died from unknown causes. Military units performed twice-daily monitoring of temperature and review of exposures and symptoms ("unit monitoring") on all persons throughout deployment, exit screening at the time of departure from Liberia, and post-deployment monitoring for 21 days at segregated, controlled monitoring areas on U.S. military installations. A total of 32 persons developed a fever during deployment from October 25, 2014, through February 27, 2015; none had a known Ebola exposure or developed Ebola infection. Monitoring of all deployed service members revealed no Ebola exposures or infections. Given their activity restrictions and comprehensive monitoring while deployed to Liberia, U.S. military personnel constitute a unique population with a lower risk for Ebola exposure compared with those working in the country without such measures.
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
Cardile,A.P., Murray,C.K., Littell,C.T., Shah,N.J., Fandre,M.N., Drinkwater,D.C., Markelz,B.P., Vento,T.J.
Original/Translated Title
URL
Date of Electronic
PMCID
Editors
Assessment of the potential for international dissemination of Ebola virus via commercial air travel during the 2014 west African outbreak 2015 Department of Medicine, Division of Infectious Diseases, University of Toronto, Toronto, ON, Canada; Divisions of Internal Medicine and Infectious Diseases, University Health Network, Toronto, ON, Canada.; Centre for Research on Inner City Health, Li Ka S
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Lancet (London, England)
Periodical, Abbrev.
Lancet
Pub Date Free Form
3-Jan
Volume
385
Issue
9962
Start Page
29
Other Pages
35
Notes
LR: 20151028; CI: Copyright (c) 2015; GR: 095066/Wellcome Trust/United Kingdom; GR: 095066/Wellcome Trust/United Kingdom; GR: R01 LM010812/LM/NLM NIH HHS/United States; GR: R01LM010812/LM/NLM NIH HHS/United States; GR: Canadian Institutes of Health Resear
Place of Publication
England
ISSN/ISBN
1474-547X; 0140-6736
Accession Number
PMID: 25458732
Language
eng
SubFile
Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't; AIM; IM
DOI
10.1016/S0140-6736(14)61828-6 [doi]
Output Language
Unknown(0)
PMID
25458732
Abstract
BACKGROUND: The WHO declared the 2014 west African Ebola epidemic a public health emergency of international concern in view of its potential for further international spread. Decision makers worldwide are in need of empirical data to inform and implement emergency response measures. Our aim was to assess the potential for Ebola virus to spread across international borders via commercial air travel and assess the relative efficiency of exit versus entry screening of travellers at commercial airports. METHODS: We analysed International Air Transport Association data for worldwide flight schedules between Sept 1, 2014, and Dec 31, 2014, and historic traveller flight itinerary data from 2013 to describe expected global population movements via commercial air travel out of Guinea, Liberia, and Sierra Leone. Coupled with Ebola virus surveillance data, we modelled the expected number of internationally exported Ebola virus infections, the potential effect of air travel restrictions, and the efficiency of airport-based traveller screening at international ports of entry and exit. We deemed individuals initiating travel from any domestic or international airport within these three countries to have possible exposure to Ebola virus. We deemed all other travellers to have no significant risk of exposure to Ebola virus. FINDINGS: Based on epidemic conditions and international flight restrictions to and from Guinea, Liberia, and Sierra Leone as of Sept 1, 2014 (reductions in passenger seats by 51% for Liberia, 66% for Guinea, and 85% for Sierra Leone), our model projects 2.8 travellers infected with Ebola virus departing the above three countries via commercial flights, on average, every month. 91,547 (64%) of all air travellers departing Guinea, Liberia, and Sierra Leone had expected destinations in low-income and lower-middle-income countries. Screening international travellers departing three airports would enable health assessments of all travellers at highest risk of exposure to Ebola virus infection. INTERPRETATION: Decision makers must carefully balance the potential harms from travel restrictions imposed on countries that have Ebola virus activity against any potential reductions in risk from Ebola virus importations. Exit screening of travellers at airports in Guinea, Liberia, and Sierra Leone would be the most efficient frontier at which to assess the health status of travellers at risk of Ebola virus exposure, however, this intervention might require international support to implement effectively. FUNDING: Canadian Institutes of Health Research.
Descriptors
Links
Book Title
Database
Publisher
Bogoch et al. Open Access article distributed under the terms of CC BY. Published by Elsevier Ltd
Data Source
Authors
Bogoch,I.I., Creatore,M.I., Cetron,M.S., Brownstein,J.S., Pesik,N., Miniota,J., Tam,T., Hu,W., Nicolucci,A., Ahmed,S., Yoon,J.W., Berry,I., Hay,S.I., Anema,A., Tatem,A.J., MacFadden,D., German,M., Khan,K.
Original/Translated Title
URL
Date of Electronic
20141021
PMCID
PMC4286618
Editors
The role of smokeless tobacco use in smoking persistence among male college students 2015 a Department of Social Sciences and Health Policy .; b Department of Biostatistical Sciences , and.; a Department of Social Sciences and Health Policy .; a Department of Social Sciences and Health Policy .; b Department of Biostatistical Sciences , and.;
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
The American Journal of Drug and Alcohol Abuse
Periodical, Abbrev.
Am.J.Drug Alcohol Abuse
Pub Date Free Form
Volume
41
Issue
6
Start Page
541
Other Pages
546
Notes
LR: 20151029; GR: R01 CA141643/CA/NCI NIH HHS/United States; JID: 7502510; NIHMS730141; OID: NLM: NIHMS730141 [Available on 11/01/16]; OID: NLM: PMC4623432 [Available on 11/01/16]; OTO: NOTNLM; PMCR: 2016/11/01 00:00; 2015/09/16 [aheadofprint]; ppublish
Place of Publication
England
ISSN/ISBN
1097-9891; 0095-2990
Accession Number
PMID: 26375618
Language
eng
SubFile
Journal Article; Observational Study; IM
DOI
10.3109/00952990.2015.1078345 [doi]
Output Language
Unknown(0)
PMID
26375618
Abstract
BACKGROUND: Significant changes in the tobacco industry have led to heightened concern about co-use of cigarettes and smokeless tobacco (SLT) products. OBJECTIVES: The aim of this study was to assess whether male cigarette smokers who also used SLT products, in the first semester of their first year of college, were more or less likely than male cigarette smokers who did not use SLT products to still be smoking by the first semester of their senior year. METHODS: Using a longitudinal, observational study, we followed a cohort of undergraduate students from 11 four-year universities in North Carolina and Virginia through their college career. Mixed-effects logistic regression analysis was conducted to estimate the likelihood of being a current smoker fall of senior year for male students who used both cigarettes and SLT at baseline, compared to those who only smoked cigarettes, after adjustment for potential confounders (n = 274). RESULTS: At baseline, 67.2% of participants were smoking cigarettes only (no SLT use) and 32.8% were dual users (cigarettes and SLT). A total of 62% were still smoking at senior year. Dual users were 30% more likely to be current smokers senior year compared to cigarette only users, although this difference was not statistically significant. Having at least one friend who smoked cigarettes and heavier cigarette smoking at baseline were significantly related to senior year smoking. CONCLUSIONS: Our findings do not support the argument that SLT use may help male college smokers discontinue their smoking habit. In fact, it may contribute to smoking persistence.
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
Wolfson,M., Suerken,C.K., Egan,K.L., Sutfin,E.L., Reboussin,B.A., Wagoner,K.G., Spangler,J.
Original/Translated Title
URL
Date of Electronic
20150916
PMCID
PMC4623432
Editors
Consumption patterns and biomarkers of exposure in cigarette smokers switched to Snus, various dissolvable tobacco products, Dual use, or tobacco abstinence 2015 R.J. Reynolds Tobacco Company, Winston-Salem, NC, USA.; R.J. Reynolds Tobacco Company, Winston-Salem, NC, USA.; R.J. Reynolds Tobacco Company, Winston-Salem, NC, USA. Electronic address: borgerm@rjrt.com.
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Regulatory toxicology and pharmacology : RTP
Periodical, Abbrev.
Regul.Toxicol.Pharmacol.
Pub Date Free Form
Mar
Volume
71
Issue
2
Start Page
186
Other Pages
197
Notes
CI: Copyright (c) 2015; JID: 8214983; 0 (Biomarkers); OTO: NOTNLM; 2014/09/03 [received]; 2014/11/25 [revised]; 2014/12/19 [accepted]; 2014/12/27 [aheadofprint]; ppublish
Place of Publication
United States
ISSN/ISBN
1096-0295; 0273-2300
Accession Number
PMID: 25549549
Language
eng
SubFile
Journal Article; Multicenter Study; Randomized Controlled Trial; Research Support, Non-U.S. Gov't; IM
DOI
10.1016/j.yrtph.2014.12.016 [doi]
Output Language
Unknown(0)
PMID
25549549
Abstract
The objectives of this clinical study were to evaluate changes in tobacco product use behavior and levels of selected biomarkers of exposure (BOEs) for smokers who switched to one of six conditions during clinical confinement: exclusive use of; Camel Snus, Sticks, Strips or Orbs, controlled Dual use of cigarettes and Camel Snus, or tobacco abstinence. The controlled Dual use (DU) condition mandated a 60% reduction in cigarettes smoked per day (CPD). 167 healthy U.S. male and female smokers were randomized to the six groups (n=25-30/group). Subjects smoked their usual brand of cigarette for 1 day prior to switching to their designated intervention condition. Levels of thirty-two BOEs in plasma, whole blood, urine and feces were determined before and after switching. Questionnaires that scored nicotine dependence and withdrawal discomfort were also administered. After 5 days, exclusive Snus, Sticks, Strips, or Orbs use averaged 6.1, 5.9, 13.5, and 8.5 units/day, respectively. DU subjects smoked 7.6 CPD and used 3.2 Snus pouches/day, on average. After 5 days, substantial reductions of most biomarkers, including nicotine, were observed in all groups. Toxicant exposures were similar to being tobacco abstinent after switching exclusively to Camel Snus, Sticks, Strips or Orbs. DU reductions were more modest.
Descriptors
Links
Book Title
Database
Publisher
The Authors. Published by Elsevier Inc
Data Source
Authors
Krautter,G.R., Chen,P.X., Borgerding,M.F.
Original/Translated Title
URL
Date of Electronic
20141227
PMCID
Editors
Risk factors on the development of new-onset gastroesophageal reflux symptoms. A population-based prospective cohort study: the HUNT study 2015 1] Institute of Clinical Research, University of Southern Denmark, Odense, Denmark [2] Department of Medical Gastroenterology S, Odense University Hospital, Odense, Denmark [3] Medical Department, Levanger Hospital, Nord-Trondelag Hospital Trust, Levanger
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
The American Journal of Gastroenterology
Periodical, Abbrev.
Am.J.Gastroenterol.
Pub Date Free Form
Mar
Volume
110
Issue
3
Start Page
393
Other Pages
400; quiz 401
Notes
JID: 0421030; 2014/09/01 [received]; 2014/12/02 [revised]; 2015/01/07 [accepted]; 2015/02/10 [aheadofprint]; ppublish
Place of Publication
United States
ISSN/ISBN
1572-0241; 0002-9270
Accession Number
PMID: 25665934
Language
eng
SubFile
Journal Article; Research Support, Non-U.S. Gov't; IM
DOI
10.1038/ajg.2015.18 [doi]
Output Language
Unknown(0)
PMID
25665934
Abstract
OBJECTIVES: Gastroesophageal reflux disease (GERD) is a highly prevalent disorder. This study assessed the risk factors of new-onset gastroesophageal reflux symptoms (GERS). METHODS: The study was based on the HUNT study, a prospective population-based cohort study conducted in 1995-1997 and 2006-2009 in Nord-Trondelag County, Norway. All inhabitants from 20 years of age were invited. Risk factors of new-onset heartburn or acid regurgitation were examined using logistic regression, providing odds ratios (OR) and 95% confidence intervals (CI). RESULTS: A total of 29,610 individuals were included (61% response rate). Participants reporting no GERS at baseline and severe GERS at follow-up (new-onset GERS; n=510) were compared with participants reporting no complaints at both times (n=14,406). Increasing age (OR 1.01 per year, 95% CI 1.00-1.02) was positively associated, whereas male sex (OR 0.81, 95% CI 0.66-0.98) and higher education (OR 0.69, 95% CI 0.56-0.86) were negatively associated with new-onset GERS. Gain in body mass index (BMI) was dose-dependently associated with new-onset GERS (OR 1.30 per unit increase in BMI, 95% CI 1.25-1.35), irrespective of baseline BMI. Previous and current tobacco smoking were associated with new-onset GERS (OR 1.37, 95% CI 1.07-1.76 and OR 1.29, 95% CI 1.00-1.67, respectively). Tobacco smoking cessation was associated with new-onset GERS among those with gain in BMI upon quitting (OR 2.03, 95% CI 1.31-3.16, with >3.5 BMI units increase). CONCLUSIONS: New-onset GERS were associated with increasing age, female sex, lower education, gain in BMI, and ever tobacco smoking. Tobacco smoking cessation was associated with new-onset GERS among those who gained weight upon quitting.
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
Hallan,A., Bomme,M., Hveem,K., Moller-Hansen,J., Ness-Jensen,E.
Original/Translated Title
URL
Date of Electronic
20150210
PMCID
Editors
Sex-stratified and age-adjusted social gradients in tobacco in Argentina and Uruguay: evidence from the Global Adult Tobacco Survey (GATS) 2015 Department of Sociology, DePaul University, Chicago, Illinois, USA.; Ministerio de Salud de la Nacion, Buenos Aires, Argentina.; Instituto Nacional de Estadistica y Censos, Ministerio de Economia y Finanzas Publicas, Buenos Aires, Argentina.; Ministerio d
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Tobacco control
Periodical, Abbrev.
Tob.Control
Pub Date Free Form
Nov
Volume
24
Issue
6
Start Page
562
Other Pages
567
Notes
CI: Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/; JID: 9209612; 0 (Tobacco Smoke Pollution); OTO: NOTNLM; 2
Place of Publication
England
ISSN/ISBN
1468-3318; 0964-4563
Accession Number
PMID: 24985731
Language
eng
SubFile
Journal Article; Research Support, Non-U.S. Gov't; IM
DOI
10.1136/tobaccocontrol-2013-051525 [doi]
Output Language
Unknown(0)
PMID
24985731
Abstract
OBJECTIVE: To examine social gradients in tobacco use in Argentina and Uruguay, using newly available directly comparable data sets. METHODS: Secondary analysis of Global Adult Tobacco Survey data from Argentina (N=6645) and Uruguay (N=5581). Social gradients in current tobacco use, exposure to secondhand smoke, and cessation attempt were examined with sex-stratified and age-adjusted logistic regression. RESULTS: Among men, there is evidence of higher odds of being a current smoker among respondents with lower levels of education, but the association is only statistically significant for respondents with less than primary education in Uruguay (OR=2.15, 95% CI 1.22 to 3.77). Similarly, women with lower levels of education have higher odds of being a current smoker in Uruguay. The association between education and exposure to secondhand smoke is broadly similar for both sexes in both countries, with generally higher odds among groups with low education, though the relationship is only statistically significant among men in Uruguay (OR=1.77, 95% CI 1.08 to 2.92). In both countries, respondents with lower levels of education in general have higher odds of having attempted to quit smoking in the past year, although these associations did not attain statistical significance. CONCLUSIONS: Social gradients in tobacco use, exposure to secondhand smoke and cessation attempts are broadly similar in both countries. Efforts to evaluate the long-term effects of tobacco control efforts in these countries should monitor how policies affect national averages, and the social gradients that are embedded in aggregate data.
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
De Maio,F.G., Konfino,J., Ondarsuhu,D., Goldberg,L., Linetzky,B., Ferrante,D.
Original/Translated Title
URL
Date of Electronic
20140701
PMCID
Editors
Standardised (plain) cigarette packaging increases attention to both text-based and graphical health warnings: experimental evidence 2015 Department of Psychology, City University London, London, UK; Barts Health NHS Trust, London, UK.; Department of Psychology, City University London, London, UK.; Department of Global Health & Development, London School of Hygiene & Tropical Medicine, Lond
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Public health
Periodical, Abbrev.
Public Health
Pub Date Free Form
Jan
Volume
129
Issue
1
Start Page
37
Other Pages
42
Notes
LR: 20160713; CI: Copyright (c) 2014; GR: 09401/Wellcome Trust/United Kingdom; GR: 100714/Wellcome Trust/United Kingdom; GR: BB/K01479X/1/Biotechnology and Biological Sciences Research Council/United Kingdom; JID: 0376507; OID: NLM: PMC4315810; OTO: NOTNL
Place of Publication
Netherlands
ISSN/ISBN
1476-5616; 0033-3506
Accession Number
PMID: 25542740
Language
eng
SubFile
Journal Article; Randomized Controlled Trial; Research Support, Non-U.S. Gov't; IM
DOI
10.1016/j.puhe.2014.10.019 [doi]
Output Language
Unknown(0)
PMID
25542740
Abstract
OBJECTIVE: To investigate whether standardised cigarette packaging increases the time spent looking at health warnings, regardless of the format of those warnings. STUDY DESIGN: A factorial (two pack styles x three warning types) within-subject experiment, with participants randomised to different orders of conditions, completed at a university in London, UK. METHODS: Mock-ups of cigarette packets were presented to participants with their branded portion in either standardised (plain) or manufacturer-designed (branded) format. Health warnings were present on all packets, representing all three types currently in use in the UK: black & white text, colour text, or colour images with accompanying text. Gaze position was recorded using a specialised eye tracker, providing the main outcome measure, which was the mean proportion of a five-second viewing period spent gazing at the warning-label region of the packet. RESULTS: An opportunity sample of 30 (six male, mean age = 23) young adults met the following inclusion criteria: 1) not currently a smoker; 2) 50% viewing time. These participants spent a greater proportion of the available time gazing at the warning-label region when the branded section of the pack was standardised (following current Australian guidelines) rather than containing the manufacturer's preferred design (mean difference in proportions = 0.078, 95% confidence interval 0.049 to 0.106, p
Descriptors
Links
Book Title
Database
Publisher
The Authors. Published by Elsevier Ltd.
Data Source
Authors
Shankleman,M., Sykes,C., Mandeville,K.L., Di Costa,S., Yarrow,K.
Original/Translated Title
URL
Date of Electronic
20141224
PMCID
PMC4315810
Editors
Crystal structure of N-[(2S,5R)-4-oxo-2,3-diphenyl-1,3-thia-zinan-5-yl]acetamide 0.375-hydrate 2015 Department of Chemistry, Pennsylvania State University, University Park, PA 16802, USA.; Pennsylvania State University, Schuylkill Campus, 200 University Drive, Schuylkill Haven, PA 17972, USA.; Pennsylvania State University, Schuylkill Campus, 200 Univer
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Acta crystallographica.Section E, Crystallographic communications
Periodical, Abbrev.
Acta Crystallogr.E.Crystallogr.Commun.
Pub Date Free Form
1-Jan
Volume
71
Issue
Pt 1
Start Page
62
Other Pages
64
Notes
LR: 20150225; JID: 101648987; OID: NLM: PMC4331885; OTO: NOTNLM; 2015/01/01 [ecollection]; 2014/11/09 [received]; 2014/12/01 [accepted]; epublish
Place of Publication
England
ISSN/ISBN
2056-9890
Accession Number
PMID: 25705452
Language
eng
SubFile
Journal Article
DOI
10.1107/S2056989014026425 [doi]
Output Language
Unknown(0)
PMID
25705452
Abstract
The asymmetric unit of the title compound, C18H18N2O2S.0.375H2O, has two independent organic mol-ecules (A and B) and 3/4 of a water mol-ecule distributed over three sites. In mol-ecule A, the 1,3-thia-zine ring is in a boat conformation, with the C atoms at the 2- and 5-positions out of the plane. The angle between the two phenyl rings is 51.70 (12) degrees . In mol-ecule B, the thia-zine ring is in a half-chair conformation, with the S atom forming the back of the half-chair. The angle between the two phenyl rings is 84.44 (14) degrees . The A mol-ecule features an intra-molecular N-Hcdots, three dots, centeredO hydrogen bond, which closes an S(5) ring motif. In the crystal, the corresponding N-H grouping of the B mol-ecule participates in an inter-molecular hydrogen bond to the A mol-ecule. The A mol-ecule participates in a C-Hcdots, three dots, centeredO inter-action back to the B mol-ecule, whilst the B mol-ecule features an intra-molecular C-Hcdots, three dots, centeredO link, which generates an S(10) loop.
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
Yennawar,H.P., Singh,H., Silverberg,L.J.
Original/Translated Title
URL
Date of Electronic
20150101
PMCID
PMC4331885
Editors
Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth-oxy-benzyl-idene)amino]-4,5,6,7-tetra-hydr o-benzo[b]thio-phene 2015 Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India.; Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA.; Department of Studies in Chemistry, University of Mysore, Manasaga
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Acta crystallographica.Section E, Crystallographic communications
Periodical, Abbrev.
Acta Crystallogr.E.Crystallogr.Commun.
Pub Date Free Form
17-Jan
Volume
71
Issue
Pt 2
Start Page
176
Other Pages
179
Notes
LR: 20150418; JID: 101648987; OID: NLM: PMC4384575; OTO: NOTNLM; 2015/02/01 [ecollection]; 2014/12/31 [received]; 2015/01/06 [accepted]; 2015/01/17 [epublish]; epublish
Place of Publication
England
ISSN/ISBN
2056-9890
Accession Number
PMID: 25878812
Language
eng
SubFile
Journal Article
DOI
10.1107/S2056989015000195 [doi]
Output Language
Unknown(0)
PMID
25878812
Abstract
In the cyclo-hexene ring of the title compound, C23H20BrNO3S, the -(CH2)4- atoms are positionally disordered [occupancy ratio = 0.753 (6):0.247 (6)]. The ring has a half-chair conformation for both the major and minor components. The dihedral angles between the mean plane of the thio-phene ring and those of the benzene and phenyl rings are 35.2 (4) and 57.7 (3) degrees , respectively. The planes of the two aryl rings are twisted with respect to each other by 86.4 (6) degrees . In the mol-ecule, there is an O-Hcdots, three dots, centeredN hydrogen bond forming an S(6) ring motif. In the crystal, mol-ecules are linked via C-Hcdots, three dots, centeredO hydrogen bonds, forming chains parallel to [100].
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
Kaur,M., Jasinski,J.P., Yathirajan,H.S., Glidewell,C., Byrappa,K.
Original/Translated Title
URL
Date of Electronic
20150117
PMCID
PMC4384575
Editors