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Title Pub Year Author Sort descending SearchLink
Prevalence of smoking among rural secondary school students in Qualyobia governorate 2003 Egyptian Smoking Prevention Research Institute.
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Journal Article
Periodical, Full
Journal of the Egyptian Society of Parasitology
Periodical, Abbrev.
J.Egypt.Soc.Parasitol.
Pub Date Free Form
Dec
Volume
33
Issue
3 Suppl
Start Page
1031
Other Pages
1050
Notes
LR: 20151119; GR: TW0594401/TW/FIC NIH HHS/United States; JID: 8102141; ppublish
Place of Publication
Egypt
ISSN/ISBN
1110-0583; 1110-0583
Accession Number
PMID: 15119469
Language
eng
SubFile
Journal Article; Multicenter Study; Research Support, U.S. Gov't, P.H.S.; IM
DOI
Output Language
Unknown(0)
PMID
15119469
Abstract
A cross sectional study was carried out in two rural secondary schools in Qualyobia governorate in the academic year 2002-2003 in order to assess the students' knowledge, attitudes and practice toward smoking. An anonymous self-administered questionnaire was used. A total of 635 students, 416 males and 219 females were interviewed. The response rate was 100%. The prevalence of ever tried cigarette was 29% (40% among males and 7% among females) with a median age of initiation at 11 years of age. The prevalence of current cigarette smoking among all students was 7.7 (11.5% among males and 0% among females). Waterpipe (Shisha) smoking was reported by 19% (26% among males and 5% among females) with median age of initiation at 12 yearsof age. The risk of smoking is higher among sons of highly educated mothers (OR=3.7, 95% CI=1-12), Boy only school students have almost half the risk of smoking than mixed school male students (OR=0.4, 95% CI=0.2-0.8). On studying the effect of having a smoker family member or friends on students smoking, having a smoker friend increases the risk of male students three time (OR=3, 95%CI=2-5) while others smoking was not statistically significant. More than 90% of the students (both males and females) thought that active and passive smoking are harmful. More females than males thought smoking is addictive (89% of the females and 81% of the males) while more males than females agreed that smokers have more friends (34% of males, 26% of the females) and that smoking makes boys look handsome (8% of males, 3% of females).
Descriptors
Adolescent, Adolescent Behavior, Cross-Sectional Studies, Egypt/epidemiology, Female, Humans, Male, Prevalence, Risk Factors, Rural Health, Smoking/epidemiology/prevention & control, Smoking Cessation, Students/statistics & numerical data, Surveys and Questionnaires
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Book Title
Database
Publisher
Data Source
Authors
Gadalla,S., Aboul-Fotouh,A., El-Setouhy,M., Mikhail,N., Abdel-Aziz,F., Mohamed,M. K., Kamal Ael,A., Israel,E.
Original/Translated Title
URL
Date of Electronic
PMCID
Editors
Perceptions of plain packaging among young adult roll-your-own smokers in France: a naturalistic approach 2015 EHESP School of Public Health, EA MOS (Equipe d'Accueil en Management des Organisations de Sante), Rennes Cx, France.; Centre for Tobacco Control Research, University of Stirling, Scotland, UK.; French National Committee Against Tobacco (CNCT), Paris, Fra
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Tobacco control
Periodical, Abbrev.
Tob.Control
Pub Date Free Form
Mar
Volume
24
Issue
e1
Start Page
e39
Other Pages
44
Notes
LR: 20151119; CI: Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.; JID: 9209612; OTO: NOTNLM; 2014/06/11 [aheadofprint];
Place of Publication
England
ISSN/ISBN
1468-3318; 0964-4563
Accession Number
PMID: 24920573
Language
eng
SubFile
Journal Article; Research Support, Non-U.S. Gov't; IM
DOI
10.1136/tobaccocontrol-2013-051513 [doi]
Output Language
Unknown(0)
PMID
24920573
Abstract
BACKGROUND: We explored, for the first time, young adult roll-your-own smokers' response to using plain packaging in real-world settings. METHODS: Naturalistic research was employed, where 133 French young adult smokers (18-25 years of age) used plain roll-your-own packs for 10 days; the plain packs they were provided with contained their usual brand of rolling tobacco and displayed the name of their usual brand. Participants were recruited in five cities in France (Paris, Marseille, Metz, Nantes, Toulouse) and completed two questionnaires to measure their response to their own branded packs and the plain packs. Both questionnaires assessed pack perceptions, brand attachment, product perceptions (eg, taste, quality, natural), feelings about smoking (satisfying, pleasurable), feelings when using the pack in front of others (embarrassment, image), warning response (credibility, awareness of risks) and smoking-related behaviour (eg, consumption, quitting). RESULTS: Compared to their own fully branded packs, plain packs were associated with less positive pack and product perceptions, lower brand attachment and less positive feelings about smoking and feelings when using the pack in front of others. Participants were also more likely to report feeling like reducing consumption and quitting when using the plain packs, and more likely to feel like missing out on rolling a cigarette. No significant differences between the two pack types (plain and branded) were found in terms of credibility of warnings and perceptions of level of tar. CONCLUSIONS: The study suggests that the impacts of plain packaging for roll-your-own cigarette smokers are the same as for smokers of factory-made cigarettes.
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
Gallopel-Morvan,K., Moodie,C., Eker,F., Beguinot,E., Martinet,Y.
Original/Translated Title
URL
Date of Electronic
20140611
PMCID
Editors
Multimodality evaluation of patients with gastroesophageal reflux disease symptoms who have failed empiric proton pump inhibitor therapy 2013 El Camino GI Medical Associates, Mountain View, California, USA.
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Diseases of the esophagus : official journal of the International Society for Diseases of the Esophagus / I.S.D.E
Periodical, Abbrev.
Dis.Esophagus
Pub Date Free Form
Jul
Volume
26
Issue
5
Start Page
443
Other Pages
450
Notes
LR: 20151119; CI: (c) 2012 Copyright the Authors. Journal compilation (c) 2012; JID: 8809160; 0 (Proton Pump Inhibitors); OTO: NOTNLM; 2012/08/02 [aheadofprint]; ppublish
Place of Publication
United States
ISSN/ISBN
1442-2050; 1120-8694
Accession Number
PMID: 22862422
Language
eng
SubFile
Journal Article; IM
DOI
10.1111/j.1442-2050.2012.01381.x [doi]
Output Language
Unknown(0)
PMID
22862422
Abstract
Patients with symptoms suggestive of gastroesophageal reflux disease (GERD), such as chest pain, heartburn, regurgitation, and dysphagia, are typically treated initially with a course of proton pump inhibitors (PPIs). The evaluation of patients who have either not responded at all or partially and inadequately responded to such therapy requires a more detailed history and may involve an endoscopy and esophageal biopsies, followed by esophageal manometry, ambulatory esophageal pH monitoring, and gastric emptying scanning. To assess the merits of a multimodality 'structural' and 'functional' assessment of the esophagus in patients who have inadequately controlled GERD symptoms despite using empiric PPI, a retrospective cohort study of patients without any response or with poor symptomatic control to empiric PPI (>2 months duration) who were referred to an Esophageal Studies Unit was conducted. Patients were studied using symptom questionnaires, endoscopy (+ or - for erosive disease, or Barrett's metaplasia) and multilevel esophageal biopsies (eosinophilia, metaplasia), esophageal motility (aperistalsis, dysmotility), 24-hour ambulatory esophageal pH monitoring (+ if % total time pH 5%), and gastric emptying scanning (+ if >10% retention at 4 hours and >70% at 2 hours). Over 3 years, 275 patients (147 men and 128 women) aged 16-89 years underwent complete multimodality testing. Forty percent (n= 109) had nonerosive reflux disease (esophagogastroduodenoscopy [EGD]-, biopsy-, pH+); 19.3% (n= 53) had erosive esophagitis (EGD+); 5.5% (n= 15) Barrett's esophagus (EGD+, metaplasia+); 5.5% (n= 15) eosinophilic esophagitis (biopsy+); 2.5% (n= 7) had achalasia and 5.8% (n= 16) other dysmotility (motility+, pH-); 16% (n= 44) had functional heartburn (EGD-, pH-), and 5.8% (n= 16) had gastroparesis (gastric scan+). Cumulative symptom scores for chest pain, heartburn, regurgitation, and dysphagia were similar among the groups (mean range 1.1-1.35 on a 0-3 scale). Multimodality evaluation changed the diagnosis of GERD in 34.5% of cases and led to or guided alternative therapies in 42%. Overlap diagnoses were frequent: 10/15 (67%) of patients with eosinophilic esophagitis, 12/16 (75%) of patients with gastroparesis, and 11/23 (48%) of patients with achalasia or dysmotility had concomitant pathologic acid reflux by pH studies. Patients with persistent GERD symptoms despite empiric PPI therapy benefit from multimodality evaluation that may change the diagnosis and guide therapy in more than one third of such cases. Because symptoms are not specific and overlap diagnoses are frequent and multifaceted, objective evidence-driven therapies should be considered in such patients.
Descriptors
Links
Book Title
Database
Publisher
Wiley Periodicals, Inc. and the International Society for Diseases of the Esophagus
Data Source
Authors
Galindo,G., Vassalle,J., Marcus,S.N., Triadafilopoulos,G.
Original/Translated Title
URL
Date of Electronic
20120802
PMCID
Editors
Squamous cell carcinoma and keratoacanthoma of the lower lip associated with 'Goza' and 'Shisha' smoking 1999 El-Hakim, I.E., Dept. of Oral/Maxillofacial Surgery, Hadayek Helwan 11433, Cairo, Egypt
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
International journal of dermatology
Periodical, Abbrev.
Int.J.Dermatol.
Pub Date Free Form
1999/
Volume
38
Issue
2
Start Page
108
Other Pages
110
Notes
Place of Publication
ISSN/ISBN
0011-9059
Accession Number
Language
SubFile
DOI
Output Language
Unknown(0)
PMID
Abstract
Background: A positive correlation between lip and buccal cancers and pipe smoking has been suggested. Various types of crude and manufactured tobacco products are consumed by smoking, chewing, and snuff dipping habits. 'Shisha' and 'Goza' smoking are widely practiced in the Middle East. The 'hubble-bubble' method and apparatus are used. These smoking habits are hazardous to health, causing obstructive lung disease, and may be important predisposing factors for the development of oral cancers. Case reports: Two cases of squamous cell carcinoma and a case of keratoacanthoma localized to the lower lip are presented in well-known 'Shisha' and 'Goza' smokers. Conclusions: 'Shisha' and 'Goza' smoking have adverse effects on general health and may predispose to oral cancer. An extensive epidemiological study should be performed to determine whether this type of smoking habit is associated with a statistically increased incidence of squamous cell carcinoma and keratoacanthoma of the lips.
Descriptors
adult, article, case report, excision, human, keratoacanthoma, lip carcinoma, lower lip, male, Middle East, mouth cancer, smoking, squamous cell carcinoma, tobacco
Links
Book Title
Database
Embase; MEDLINE
Publisher
Data Source
Embase
Authors
El-Hakim,I. E., Uthman,M. A. E.
Original/Translated Title
URL
Date of Electronic
PMCID
Editors
Sexual reproduction in the white pine weevil (Pissodes strobi [Peck] [Coleoptera: Curculionidae]): Implications for population genetic diversity 2002 El-Kassaby, Y.A., Department of Forest Sciences, University of British Columbia, Vancouver, BC V6T 1Z4, Canada
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Journal of Heredity
Periodical, Abbrev.
J.Hered.
Pub Date Free Form
/
Volume
93
Issue
3
Start Page
165
Other Pages
169
Notes
Place of Publication
ISSN/ISBN
0022-1503
Accession Number
Language
SubFile
DOI
Output Language
Unknown(0)
PMID
Abstract
Controlled mating experiments in the white pine weevil (Pissodes strobi [Peck]) indicated that female weevils either stored sperm or fertilized eggs from one season to the next, and were able to colonize Sitka spruce (Picea sitchensis [Bong.] Carr.) trees without additional mating events. This was interpreted as being beneficial for the insect, in that population establishment in a new habitat could be initiated by dispersing previously mated females without participation of the male. This makes colonization and population/outbreak development more likely as it reduces the need for mate searching in the second season. Paternity identification, based on microsatellite molecular markers, established that the progeny produced in year 2 by females mated only in year 1, were often fathered by more than one male. Multiple paternity, coupled with a lack of parthenogenesis, which was also demonstrated herein, may help to account for the high degree of genetic diversity evidenced in this species.
Descriptors
article, beetle, dispersion, female, genetic variability, genotype, male, mating, microsatellite marker, nonhuman, parthenogenesis, paternity, population genetics, priority journal, reproduction
Links
Book Title
Database
Embase; MEDLINE
Publisher
Data Source
Embase
Authors
Lewis,K. G., Liewlaksaneeyanawin,C., Alfaro,R. I., Ritland,C., Ritland,K., El-Kassaby,Y. A.
Original/Translated Title
URL
Date of Electronic
PMCID
Editors
Hepatitis C virus infection at Sharkia Governorate, Egypt: seroprevalence and associated risk factors. 2004 el-Sadawy, M., Faculty of Medicine, Zagazig University, Zagazig.
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Journal of the Egyptian Society of Parasitology
Periodical, Abbrev.
J.Egypt.Soc.Parasitol.
Pub Date Free Form
/
Volume
34
Issue
1 Suppl
Start Page
367
Other Pages
384
Notes
Place of Publication
ISSN/ISBN
0253-5890
Accession Number
Language
SubFile
DOI
Output Language
Unknown(0)
PMID
Abstract
Because many persons with chronic hepatitis C virus (HCV) infection are asymptomatic, population based serologic studies are needed to estimate the prevalence of infection and to develop and evaluate prevention efforts. A sample of 1422 individuals was included in the study by using multistage sampling technique. Their age ranged from 4-78 years with a mean age (34.7 +/- 18.5), 782 were males (55%) and 640 were females (45%). Exposures and demographic characteristics were obtained through a predesigned questionnaire. Antibody to HCV was assessed using micro-particle enzyme immunoassay (MEIA) enzyme assay by IMX, and the HCV RNA was tested by Real-time PCR technique using ABI Prism 7700 system. The seroprevalence of antibodies to HCV were 23.4% and 27.4% in urban and rural areas respectively, with an overall prevalence (25.8%). This reflects prior HCV infection but not necessarily a current liver disease. Prevalence was higher among males than females and increased sharply with age, from 4.8% in those or = 40 years). Those who were not educated and farmers had a significantly high prevalence. The significant predictors of HCV infection were previous parenteral therapy for schistosomiasis (OR = 4.3, 95% CI = 3.6-7.9), among those over 20 years of age (3.5, 2.18-5.8), blood transfusion (4.1, 2.4-6.9), invasive procedures (surgery and endoscopy), and use of contaminated syringes and needles. Also, shaving at community barbers added significance to the model. Exposures not significantly related to HCV seropositivity were gender, active infection with Schistosoma mansoni, sutures or intravenous and urinary catheterization, water pipe "goza" smoking in group.
Descriptors
hepatitis C antibody, virus RNA, adolescent, adult, age, aged, article, blood, child, Egypt, epidemiology, female, genetics, hepatitis C, Hepatitis C virus, human, immunology, male, middle aged, preschool child, risk factor, sex difference, socioeconomics
Links
Book Title
Database
MEDLINE
Publisher
Data Source
Embase
Authors
el-Sadawy,M., Ragab,H., el-Toukhy,H., el-Mor,A. L., Mangoud,A. M., Eissa,M. H., Afefy,A. F., el-Shorbagy,E., Ibrahem,I. A., Mahrous,S., Abdel-Monem,A., Sabee,E. I., Ismail,A., Morsy,T. A., Etewa,S., Nor Edin,E., Mostafa,Y., Abouel-Magd,Y., Hassan,M. I., Lakouz,K., Abdel-Aziz,K., el-Hady,G., Saber,M.
Original/Translated Title
URL
Date of Electronic
PMCID
Editors
Energy efficient cooperation in underlay RFID cognitive networks for a water smart home 2014 Electrical and Computer Engineering Department, Texas A&M University at Qatar, Doha 23874, Qatar. adnan.nasir@qu.edu.qa.; Electrical and Computer Engineering Department, Texas A&M University at Qatar, Doha 23874, Qatar. syed.hussain@qatar.tamu.edu.; Schoo
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Sensors (Basel, Switzerland)
Periodical, Abbrev.
Sensors (Basel)
Pub Date Free Form
30-Sep
Volume
14
Issue
10
Start Page
18353
Other Pages
18369
Notes
JID: 101204366; 059QF0KO0R (Water); OID: NLM: PMC4239936; 2014/04/13 [received]; 2014/09/15 [revised]; 2014/09/23 [accepted]; epublish
Place of Publication
Switzerland
ISSN/ISBN
1424-8220; 1424-8220
Accession Number
PMID: 25271565
Language
eng
SubFile
Journal Article; Research Support, Non-U.S. Gov't; IM
DOI
10.3390/s141018353 [doi]
Output Language
Unknown(0)
PMID
25271565
Abstract
Shrinking water resources all over the world and increasing costs of water consumption have prompted water users and distribution companies to come up with water conserving strategies. We have proposed an energy-efficient smart water monitoring application in [1], using low power RFIDs. In the home environment, there exist many primary interferences within a room, such as cell-phones, Bluetooth devices, TV signals, cordless phones and WiFi devices. In order to reduce the interference from our proposed RFID network for these primary devices, we have proposed a cooperating underlay RFID cognitive network for our smart application on water. These underlay RFIDs should strictly adhere to the interference thresholds to work in parallel with the primary wireless devices [2]. This work is an extension of our previous ventures proposed in [2,3], and we enhanced the previous efforts by introducing a new system model and RFIDs. Our proposed scheme is mutually energy efficient and maximizes the signal-to-noise ratio (SNR) for the RFID link, while keeping the interference levels for the primary network below a certain threshold. A closed form expression for the probability density function (pdf) of the SNR at the destination reader/writer and outage probability are derived. Analytical results are verified through simulations. It is also shown that in comparison to non-cognitive selective cooperation, this scheme performs better in the low SNR region for cognitive networks. Moreover, the hidden Markov model's (HMM) multi-level variant hierarchical hidden Markov model (HHMM) approach is used for pattern recognition and event detection for the data received for this system [4]. Using this model, a feedback and decision algorithm is also developed. This approach has been applied to simulated water pressure data from RFID motes, which were embedded in metallic water pipes.
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
Nasir,A., Hussain,S.I., Soong,B.H., Qaraqe,K.
Original/Translated Title
URL
Date of Electronic
20140930
PMCID
PMC4239936
Editors
Online E-cigarette Marketing Claims: A Systematic Content and Legal Analysis 2016 Elizabeth G. Klein, Associate Professor, The Ohio State University College of Public Health, Columbus, OH. Micah Berman, Assistant Professor, The Ohio State University College of Public Health and Moritz College of Law, Columbus, OH. Natalie Hemmerich, Po
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Tobacco regulatory science
Periodical, Abbrev.
Tob Regul.Sci.
Pub Date Free Form
Jul
Volume
2
Issue
3
Start Page
252
Other Pages
262
Notes
LR: 20160725; GR: P50 CA180908/CA/NCI NIH HHS/United States; JID: 101655763; NIHMS799718; OTO: NOTNLM; 2016/07/01 [epublish]; ppublish
Place of Publication
ISSN/ISBN
2333-9748; 2333-9748
Accession Number
PMID: 27446984
Language
ENG
SubFile
JOURNAL ARTICLE
DOI
10.18001/TRS.2.3.5 [doi]
Output Language
Unknown(0)
PMID
27446984
Abstract
OBJECTIVES: Electronic nicotine delivery systems (ENDS), or e-cigarettes, are heavily marketed online. The purpose of our study was to perform a systematic identification and evaluation of claims made within ENDS retailer and manufacturer websites, and the legal status of such claims. METHODS: We employed a systematic search protocol with popular search engines using 6 terms: (1) e-cigarettes; (2) e-cigs; (3) e-juice; (4) e-liquid; (5) e-hookah; and (6) vape pen. We analyzed English-language websites where ENDS are sold for implicit and explicit health-related claims. A legal analysis determined whether such claims are permissible under the US Food and Drug Administration's regulations. RESULTS: The vast majority of ENDS manufacturer (N = 78) and retailer (N = 32) websites made at least one health-related claim (77% and 65%, respectively). Modified risk claims and secondhand smoke-related claims were most prevalent, with an average of 2 claims per site. CONCLUSIONS: Health-related claims are plentiful within ENDS manufacturer and retailer websites. Results demonstrate that these sites focus on potential benefits while minimizing or eliminating information about possible harmful effects of ENDS. These claims are subject to the current regulatory authority by the FDA, and pose a risk of misinforming consumers.
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
Klein,E.G., Berman,M., Hemmerich,N., Carlson,C., Htut,S., Slater,M.
Original/Translated Title
URL
Date of Electronic
20160701
PMCID
PMC4950517
Editors
Carbon Monoxide Poisoning Caused by Water Pipe Smoking: A Case Series 2016 Emergency Department, Medical Centre Haaglanden, The Hague, The Netherlands.
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
The Journal of emergency medicine
Periodical, Abbrev.
J.Emerg.Med.
Pub Date Free Form
5-Jul
Volume
Issue
Start Page
Other Pages
Notes
LR: 20160711; CI: Copyright (c) 2016; JID: 8412174; OTO: NOTNLM; 2016/01/13 [received]; 2016/04/14 [revised]; 2016/05/17 [accepted]; aheadofprint
Place of Publication
ISSN/ISBN
0736-4679; 0736-4679
Accession Number
PMID: 27397765
Language
ENG
SubFile
JOURNAL ARTICLE
DOI
S0736-4679(16)30176-7 [pii]
Output Language
Unknown(0)
PMID
27397765
Abstract
BACKGROUND: Carbon monoxide-related symptoms caused by water pipe smoking may be a frequent occurrence. This might often be overlooked, because patients will not always identify the smoke exposure as the cause of their presenting complaints and may well withhold this information. CASE REPORT: A series of three patients who were 15 to 28 years of age presented to the emergency department with nonspecific symptoms and were found to have carbon monoxide poisoning from water pipe smoking. WHY SHOULD AN EMERGENCY PHYSICIAN BE AWARE OF THIS?: This case series might improve recognition of this phenomenon. Carbon monoxide poisoning can cause serious problems, yet it could be easily diagnosed and treated. Identifying this condition can expedite treatment and prevent unnecessary diagnostic tests in an attempt to explain its symptoms.
Descriptors
Links
Book Title
Database
Publisher
Elsevier Inc
Data Source
Authors
Veen,M.
Original/Translated Title
URL
Date of Electronic
20160705
PMCID
Editors
Solid-phase microextraction measurement of parent and alkyl polycyclic aromatic hydrocarbons in milliliter sediment pore water samples and determination of K(DOC) values 2005 Energy and Environmental Research Center, University of North Dakota, Grand Forks, North Dakota 58202, USA. shawthorne@undeerc.org
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Environmental science & technology
Periodical, Abbrev.
Environ.Sci.Technol.
Pub Date Free Form
15-Apr
Volume
39
Issue
8
Start Page
2795
Other Pages
2803
Notes
LR: 20121115; JID: 0213155; 0 (Benzopyrenes); 0 (Colloids); 0 (Fluorenes); 0 (Organic Chemicals); 0 (Polycyclic Hydrocarbons, Aromatic); 0 (Water Pollutants, Chemical); 360UOL779Z (fluoranthene); 7440-44-0 (Carbon); ppublish
Place of Publication
United States
ISSN/ISBN
0013-936X; 0013-936X
Accession Number
PMID: 15884378
Language
eng
SubFile
Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.; IM
DOI
Output Language
Unknown(0)
PMID
15884378
Abstract
The U.S. Environmental Protection Agency (EPA) narcosis model for benthic organisms in polycyclic aromatic hydrocarbon (PAH) contaminated sediments requires the measurement of 18 parent PAHs and 16 groups of alkyl PAHs ("34" PAHs) in pore water with desired detection limits as low as nanograms per liter. Solid-phase microextraction (SPME) with gas chromatographic/mass spectrometric (GC/ MS) analysis can achieve such detection limits in small water samples, which greatly reduces the quantity of sediment pore water that has to be collected, shipped, stored, and prepared for analysis. Four sediments that ranged from urban background levels (50 mg/kg total "34" PAHs) to highly contaminated (10 000 mg/kg total PAHs) were used to develop SPME methodology for the "34" PAH determinations with only 1.5 mL of pore water per analysis. Pore water was obtained by centrifuging the wet sediment, and alum flocculation was used to remove colloids. Quantitative calibration was simplified by adding 15 two- to six-ring perdeuterated PAHs as internal standards to the water calibration standards and the pore water samples. Response factors for SPME followed by GC/MS were measured for 22 alkyl PAHs compared to their parent PAHs and used to calibrate for the 18 groups of alkyl PAHs. Dissolved organic carbon (DOC) ranging from 4 to 27 mg/L had no measurable effect on the freely dissolved concentrations of two- and three-ring PAHs. In contrast, 5-80% of the total dissolved four- to six-ring PAHs were associated with the DOC rather than being freely dissolved, corresponding to DOC/water partitioning coefficients (K(DOC)) with log K(DOC) values ranging from 4.1 (for fluoranthene) to 5.6 (for benzo[ghi]perylene). However, DOC-associated versus freely dissolved PAHs had no significant effect on the total "34" PAH concentrations or the sum of the "toxic units" (calculated bythe EPA protocol), since virtually all (86-99%) of the dissolved PAH concentrations and toxic units were contributed by two- and three-ring PAHs.
Descriptors
Benzopyrenes/analysis, Calibration, Carbon/analysis, Colloids/isolation & purification, Environmental Monitoring/methods, Flocculation, Fluorenes/analysis, Gas Chromatography-Mass Spectrometry, Geologic Sediments/analysis/chemistry, Nanotechnology, Organic Chemicals/analysis, Polycyclic Hydrocarbons, Aromatic/analysis, Porosity, Water Pollutants, Chemical/analysis
Links
Book Title
Database
Publisher
Data Source
Authors
Hawthorne,S. B., Grabanski,C. B., Miller,D. J., Kreitinger,J. P.
Original/Translated Title
URL
Date of Electronic
PMCID
Editors