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Effects of various methods of chlorhexidine application on shear bond strength 1998 College of Dentistry, University of Iowa, Iowa City 52242, USA.
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
American Journal of Orthodontics and Dentofacial Orthopedics : Official Publication of the American Association of Orthodontists, its Constituent Societies, and the American Board of Orthodontics
Periodical, Abbrev.
Am.J.Orthod.Dentofacial Orthop.
Pub Date Free Form
Aug
Volume
114
Issue
2
Start Page
150
Other Pages
153
Notes
LR: 20131121; JID: 8610224; 0 (Anti-Infective Agents, Local); 0 (Drug Combinations); 0 (Parogencyl); 0 (Resin Cements); 0 (Toothpastes); 0 (chlorhexidine, thymol drug combination); 12597-68-1 (Stainless Steel); 135669-49-7 (Transbond); 3J50XA376E (Thymol)
Place of Publication
UNITED STATES
ISSN/ISBN
0889-5406; 0889-5406
Accession Number
PMID: 9714279
Language
eng
SubFile
Comparative Study; Journal Article; D; IM
DOI
S0889-5406(98)00176-0 [pii]
Output Language
Unknown(0)
PMID
9714279
Abstract
Chlorhexidine has been applied on the teeth and over orthodontic appliances during treatment in order to reduce bacterial colonization. The purpose of this study was to determine whether the application of chlorhexidine with or without a sealant, to the etched enamel will affect the shear bond strength and the bracket/adhesive failure modes of orthodontic brackets. A total of 132 extracted third molars were cleaned and then divided into 6 groups of at least 20 teeth each. The teeth were etched with a 37% phosphoric acid gel and a sealant was applied in 5 of the groups. Stainless steel orthodontic brackets were then bonded with the Transbond XT bonding system. The chlorhexidine was applied to the teeth either as a prophylactic paste or as a varnish under the following conditions: (1) as a varnish over the bracket and tooth surfaces after the bonding procedure was completed; (2) as a prophylactic paste containing 0.12% chlorhexidine over the intact enamel i.e., before etching; (3) mixed with the sealant and applied to the etched enamel before bonding, (4) as a varnish applied to the etched enamel with no sealant used; (5) as a varnish over the light cured sealant; and (6) as a varnish over the sealant before the sealant was light cured. All teeth were mounted in phenolic rings and stored in deionized water at 37 degrees C for 48 hours. A Zwick Universal Testing Machine was used to determine shear bond strengths. The residual adhesive on the enamel surface was evaluated with the Adhesive Remnant Index. The analysis of variance and chi square tests were used to compare the six groups. Significance was predetermined at the p < or = 0.05. The findings in this study indicated that shear bond strength was not significantly affected when chlorhexidine was applied; (1) over the bracket and tooth surfaces after the bonding procedure was completed (mean = 12.3 +/- 3.1 MPa), (2) as a prophylactic paste over the unetched enamel surface before the bonding procedure is initiated (mean = 9.6 +/- 2.3 MPa), and (3) when the varnish was premixed with the sealant and applied on the etched enamel surface (mean 11.8 +/- 2.1 MPa). On the other hand, in all the experimental groups in which the chlorhexidine varnish was applied as a layer on the etched enamel surface or over the sealant, shear bond strength values and bracket failure rates were of a magnitude that made them clinically unacceptable.
Descriptors
Acid Etching, Dental, Analysis of Variance, Anti-Infective Agents, Local, Bisphenol A-Glycidyl Methacrylate, Chi-Square Distribution, Chlorhexidine/administration & dosage/chemistry, Dental Bonding, Dental Debonding, Dental Enamel, Dental Stress Analysis, Drug Combinations, Humans, Lacquer, Materials Testing, Orthodontic Brackets, Resin Cements, Stainless Steel, Statistics, Nonparametric, Tensile Strength, Thymol/chemistry, Toothpastes
Links
Book Title
Database
Publisher
Data Source
Authors
Bishara,S. E., Vonwald,L., Zamtua,J., Damon,P. L.
Original/Translated Title
URL
Date of Electronic
PMCID
Editors
Unconventional materials and substances used in water pipe (narghile) by smokers in central western region of Saudi Arabia 2014 College of Dentistry, Taibah University, Al Madinah Al Monawara, PO Box 344, Postal Code 30001, Kingdom of Saudi Arabia. E-mail. deoaah@yahoo.com.
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Saudi medical journal
Periodical, Abbrev.
Saudi Med.J.
Pub Date Free Form
Aug
Volume
35
Issue
8
Start Page
890
Other Pages
893
Notes
JID: 7909441; ppublish
Place of Publication
Saudi Arabia
ISSN/ISBN
0379-5284; 0379-5284
Accession Number
PMID: 25129195
Language
eng
SubFile
Journal Article; IM
DOI
Output Language
Unknown(0)
PMID
25129195
Abstract
OBJECTIVES: To investigate the use of unconventional substances and materials in water pipe among cafe water pipe smokers. METHODS: This was a questionnaire-based survey among subjects attending coffee shops in the region of Al Madinah, Saudi Arabia between February and March 2013. RESULTS: We invited 110 subjects, only 90 consented to participate in the study. A percentage of 1.1% used fluids other than water in the water pipe tank, 18.9% added other soft drinks to the tank, and 7.8% added flowers, spices or drugs to the tobacco mix placed in the head of the water pipe. A proportion of participants used fruits to replace the water pipe head (12.2%), or to replace water pipe tank (4.4%). Higher number of children the smokers had and cafe smoking were all significantly associated with unconventional practices. CONCLUSION: A substantial percentage of sample of water pipe smokers in Al Madinah, Saudi Arabia use unusual materials and/or substances in the water pipe and this is probably encouraged by cafe smoking.
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
Baboor,A.S., Alnazzawi,A.A., Abu-Hammad,O.A., Dar-Odeh,N.S.
Original/Translated Title
URL
Date of Electronic
PMCID
Editors
Smoking among dental students at King Saud University: Consumption patterns and risk factors 2014 College of Dentistry-King Saud University, Riyadh, Saudi Arabia.; College of Dentistry-King Saud University, Riyadh, Saudi Arabia.; College of Dentistry-King Saud University, Riyadh, Saudi Arabia.
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
The Saudi dental journal
Periodical, Abbrev.
Saudi Dent.J.
Pub Date Free Form
Jul
Volume
26
Issue
3
Start Page
88
Other Pages
95
Notes
LR: 20140728; JID: 9313603; OID: NLM: PMC4095047; OTO: NOTNLM; 2013/11/07 [received]; 2014/02/21 [revised]; 2014/03/31 [accepted]; 2014/05/14 [epublish]; ppublish
Place of Publication
Saudi Arabia
ISSN/ISBN
1013-9052; 1013-9052
Accession Number
PMID: 25057228
Language
eng
SubFile
Journal Article
DOI
10.1016/j.sdentj.2014.03.003 [doi]
Output Language
Unknown(0)
PMID
25057228
Abstract
OBJECTIVE: To assess smoking prevalence among dental students at King Saud University (KSU) and to determine possible risk factors of tobacco use. METHODS: A self-addressed invitation letter was sent to all dental students (males and females) at KSU requesting participation in this study. Data on smoking habits, associated risk factors, and demographic factors, such as age, marital status, residency status, the student's year of study, and grade point average, were collected by an electronic self-administered questionnaire sent via email. Data were analyzed using SPSS. Significant differences between different groups were assessed with a Pearson Chi-Square test at alpha = 0.05. Logistic regression analysis was used to calculate the odds ratio (OR) and 95% confidence interval (95% CI) and to determine the effect of different risk factors on students' smoking habits. RESULTS: Of the 600 registered dental students, 400 students responded (230 males, 170 females), representing a response rate of 67%. More male than female students were current smokers (27.6% vs. 2.4%, p
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
AlSwuailem,A.S., AlShehri,M.K., Al-Sadhan,S.
Original/Translated Title
URL
Date of Electronic
20140514
PMCID
PMC4095047
Editors
Evaluation of periodontal status in subjects with hyperlipidemia 2010 College of Dentistry at King Saud University in Riyadh, Saudi Arabia. fawartani@hotmail.com
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
The journal of contemporary dental practice
Periodical, Abbrev.
J.Contemp.Dent.Pract.
Pub Date Free Form
1-Mar
Volume
11
Issue
2
Start Page
33
Other Pages
40
Notes
LR: 20131121; JID: 101090552; 0 (Cholesterol, HDL); 0 (Cholesterol, LDL); 0 (Triglycerides); 97C5T2UQ7J (Cholesterol); epublish
Place of Publication
United States
ISSN/ISBN
1526-3711; 1526-3711
Accession Number
PMID: 20228985
Language
eng
SubFile
Comparative Study; Journal Article; D; IM
DOI
1526-3711-673 [pii]
Output Language
Unknown(0)
PMID
20228985
Abstract
AIM: The aim of this study was to evaluate the periodontal status in subjects with hyperlipidemia and to determine whether there is any association between hyperlipidemia and periodontal disease. METHODS AND MATERIALS: Sixty female patients were enrolled in the study; group one is hyperlipidemic patients (30 subjects) and group 2 is systemically fit patients within the same age group (control; 30 subjects). In both groups body mass index (BMI) and clinical parameters were measured; plaque index (PI), bleeding on probing (BOP), pocket depth (PPD) as well as clinical attachment level (CAL) and biochemical parameters, including plasma triglyceride, total cholesterol, low-density lipoprotein cholesterol (LDL-C), and high-density lipoprotein cholesterol (HDL-C) levels, were evaluated. RESULTS: The mean values of BMI, PPD, CAL, PI (%), and BOP (%) for the hyperlipidemia group were significantly higher than those for the control group. Total cholesterol and LDL-C levels were significantly and positively associated with CAL. Plasma triglyceride level was significantly associated with PPD and CAL. CONCLUSIONS: The results of our study showed that female patients with hyperlipidemia had higher values of periodontal parameters compared to control individuals. However, in the future studies with larger sample sizes in mixed gender populations are needed to determine the association between hyperlipidemia and periodontal disease. CLINICAL SIGNIFICANCE: The results of our study showed that female patients with hyperlipidemia might manifest clinically higher values of periodontal parameters compared to nonlipdemic individuals. However, due to the small sample size of this study the exact association between hyperlipidemia and periodontal disease is still uncertain. Care has to be taken with a hyperlipidemia patients and advice can be given to them for periodic periodontal checkup.
Descriptors
Adult, Body Mass Index, Case-Control Studies, Cholesterol/blood, Cholesterol, HDL/blood, Cholesterol, LDL/blood, Cross-Sectional Studies, Dental Plaque Index, Female, Gingival Hemorrhage/classification, Humans, Hyperlipidemias/blood/complications, Middle Aged, Periodontal Attachment Loss/classification, Periodontal Diseases/complications, Periodontal Index, Periodontal Pocket/classification, Social Class, Triglycerides/blood
Links
Book Title
Database
Publisher
Data Source
Authors
Awartani,F., Atassi,F.
Original/Translated Title
URL
Date of Electronic
20100301
PMCID
Editors
Assessing the Effect of Waterpipe Smoking on Cancer Outcome - a Systematic Review of Current Evidence 2017 College of Dental Medicine, Roseman University of Health Sciences, South Jordan, Utah 84095, United States. Email:kamranhabibawan@gmail.com
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Asian Pacific journal of cancer prevention : APJCP
Periodical, Abbrev.
Asian Pac.J.Cancer.Prev.
Pub Date Free Form
1-Feb
Volume
18
Issue
2
Start Page
495
Other Pages
502
Notes
LR: 20181113; CI: Creative Commons Attribution License; JID: 101130625; OTO: NOTNLM; 2017/03/28 06:00 [pubmed]; 2017/03/28 06:00 [medline]; 2017/03/28 06:00 [entrez]; epublish
Place of Publication
Thailand
ISSN/ISBN
2476-762X; 1513-7368
Accession Number
PMID: 28345836
Language
eng
SubFile
Journal Article
DOI
10.22034/APJCP.2017.18.2.495 [doi]
Output Language
Unknown(0)
PMID
28345836
Abstract
Background: Waterpipe smoking (WPS) is widely believed to be a safe and hazard-free tobacco habit. However, a number of studies have indicated that exposure to several toxicants and carcinogens through WPS is strongly related to serious health hazards. The current paper presents a narrative review on the effects of WPS on cancer outcome. Methods: The addressed focused question was "Is there an association between waterpipe smoking and cancer outcome?" PubMed, Medline, EMBASE, ISI Web of Science and the Cochrane databases were searched until June 2015 using the key words "Waterpipe", "Hookah", "Narghileh", "Shisha", "Hubbly Bubbly" "cancer" in various combinations. Letters to the Editor, review articles, case-reports and unpublished articles were excluded. Results: A total of 16 studies were included: six on lung cancer, three on oesophageal cancer, two on gastric cancer, two on bladder cancer, and one each on nasopharyngeal, pancreatic and prostate cancers. Our search did not yield any study that evaluated the risk of oral cancer in WPS users. The available evidence showed a significant association of WPS with lung cancer (UOR 6.0, 95% CI 1.78-20.26); however, no association was observed with bladder, nasopharyngeal, pancreatic and prostate cancers. Gastric (OR 3.4, 95% CI 1.7-7.1) and oesophageal cancers (OR 1.85, 95% CI 1.41-2.44) were observed to have weak associations with WPS. Conclusion: Regardless of the limitations, there is sufficient evidence to suggest associations of WPS with cancer, particularly in the lung. Future well-designed studies are required to identify and quantify with confidence all the health effects of this form of smoking.
Descriptors
Links
Book Title
Database
Publisher
Data Source
Authors
Awan,K.H., Siddiqi,K., Patil,Sh, Hussain,Q.A.
Original/Translated Title
URL
Date of Electronic
20170201
PMCID
PMC5454749
Editors
Multiwalled carbon nanotubes as adsorbents of solid-phase extraction for determination of polycyclic aromatic hydrocarbons in environmental waters coupled with high-performance liquid chromatography 2007 College of Chemistry and Chemical Engineering, Southwest University, The Key Laboratory of Eco-environments in Three Gorges Reservoir Region, Ministry of Education, Chongqing 400715, China.
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Journal of chromatography.A
Periodical, Abbrev.
J.Chromatogr.A
Pub Date Free Form
30-Nov
Volume
1173
Issue
2-Jan
Start Page
27
Other Pages
36
Notes
LR: 20090115; JID: 9318488; 0 (Nanotubes, Carbon); 0 (Polycyclic Hydrocarbons, Aromatic); 0 (Water Pollutants, Chemical); 2007/08/06 [received]; 2007/10/09 [revised]; 2007/10/10 [accepted]; 2007/10/16 [aheadofprint]; ppublish
Place of Publication
Netherlands
ISSN/ISBN
0021-9673; 0021-9673
Accession Number
PMID: 17977550
Language
eng
SubFile
Journal Article; Research Support, Non-U.S. Gov't; IM
DOI
S0021-9673(07)01771-2 [pii]
Output Language
Unknown(0)
PMID
17977550
Abstract
Multiwalled carbon nanotubes (MWCNTs) were used as a novel kind of solid-phase extraction adsorbents in this work as well as an analytical method based on MWCNTs solid-phase extraction (SPE) combined with high-performance liquid chromatography (HPLC) was established for the determination of polycyclic aromatic hydrocarbons (PAHs), some of which belong to typical persistent organic pollutants (POPs) owing to their carcinogenicity and endocrine disrupting activity. Several conditions that probably affected the extraction efficiency including the eluent volume, sample flow rate, sample pH and the sample volume were optimized in detail. The characteristic data of analytical performance were determined to investigate the sensitivity and precision of the method, and the method was applied to the determination of PAHs in environmental water samples such as river water sample, tap water sample and wastewater sample from the constructed wetland effluent. The experimental results indicated that there were excellent linear relationship between peak area and the concentration of PAHs over the range of 0.04-100 microg L(-1), and the precisions (RSD) were 1.7-4.8% under the optimal conditions. The detection limits of proposed method for the studied PAHs were 0.005-0.058 microg L(-1) (S/N=3). The recoveries of PAHs spiked in environmental water samples ranged from 78.7 to 118.1%. It was concluded that MWCNTs packed cartridge coupled with HPLC was an excellent alternative for the routine analysis of PAHs at trace level.
Descriptors
Chromatography, High Pressure Liquid/methods, Nanotubes, Carbon, Polycyclic Hydrocarbons, Aromatic/analysis/chemistry, Reproducibility of Results, Solid Phase Extraction/methods, Water Pollutants, Chemical/analysis/chemistry
Links
Book Title
Database
Publisher
Data Source
Authors
Wang,W. D., Huang,Y. M., Shu,W. Q., Cao,J.
Original/Translated Title
URL
Date of Electronic
20071016
PMCID
Editors
Fabrication and application of zinc-zinc oxide nanosheets coating on an etched stainless steel wire as a selective solid-phase microextraction fiber 2015 College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.; College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.; College of Chemistry and Chemical Engineering, Northwes
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Journal of chromatography.A
Periodical, Abbrev.
J.Chromatogr.A
Pub Date Free Form
6-Mar
Volume
1384
Issue
Start Page
28
Other Pages
36
Notes
CI: Copyright (c) 2015; JID: 9318488; 0 (Polycyclic Hydrocarbons, Aromatic); 0 (Water Pollutants, Chemical); 059QF0KO0R (Water); 12597-68-1 (Stainless Steel); J41CSQ7QDS (Zinc); SOI2LOH54Z (Zinc Oxide); OTO: NOTNLM; 2014/11/24 [received]; 2015/01/20 [revi
Place of Publication
Netherlands
ISSN/ISBN
1873-3778; 0021-9673
Accession Number
PMID: 25662065
Language
eng
SubFile
Journal Article; Research Support, Non-U.S. Gov't; IM
DOI
10.1016/j.chroma.2015.01.059 [doi]
Output Language
Unknown(0)
PMID
25662065
Abstract
A novel zinc-zinc oxide (Zn-ZnO) nanosheets coating was directly fabricated on an etched stainless steel wire substrate as solid-phase microextraction (SPME) fiber via previous electrodeposition of robust Zn coating. The scanning electron micrograph of the Zn-ZnO nanosheets coated fiber exhibits a flower-like nanostructure with high surface area. The SPME performance of as-fabricated fiber was investigated for the concentration and determination of polycyclic aromatic hydrocarbons, phthalates and ultraviolet (UV) filters coupled to high performance liquid chromatography with UV detection (HPLC-UV). It was found that the Zn-ZnO nanosheets coating exhibited high extraction capability, good selectivity and rapid mass transfer for some UV filters. The main parameters affecting extraction performance were investigated and optimized. Under the optimized conditions, the calibration graphs were linear over the range of 0.1-200mugL(-1). The limits of detection of the proposed method were 0.052-0.084mugL(-1) (S/N=3). The single fiber repeatability varied from 5.18% to 7.56% and the fiber-to-fiber reproducibility ranged from 6.74% to 8.83% for the extraction of spiked water with 50mugL(-1) UV filters (n=5). The established SPME-HPLC-UV method was successfully applied to the selective concentration and sensitive determination of target UV filters from real environmental water samples with recoveries from 85.8% to 105% at the spiking level of 10mugL(-1) and 30mugL(-1). The relative standard deviations were below 9.7%.
Descriptors
Links
Book Title
Database
Publisher
. Published by Elsevier B.V
Data Source
Authors
Song,W., Guo,M., Zhang,Y., Zhang,M., Wang,X., Du,X.
Original/Translated Title
URL
Date of Electronic
20150125
PMCID
Editors
Phenyl-functionalization of titanium dioxide-nanosheets coating fabricated on a titanium wire for selective solid-phase microextraction of polycyclic aromatic hydrocarbons from environment water samples 2015 College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.; College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China.; College of Chemistry and Chemical Engineering, Northwes
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Talanta
Periodical, Abbrev.
Talanta
Pub Date Free Form
1-Nov
Volume
144
Issue
Start Page
998
Other Pages
1006
Notes
CI: Copyright (c) 2015; JID: 2984816R; 0 (Polycyclic Hydrocarbons, Aromatic); 0 (Thioglycolates); 0 (Waste Water); 0 (Water Pollutants, Chemical); 15FIX9V2JP (titanium dioxide); 7857H94KHM (2-mercaptoacetate); D1JT611TNE (Titanium); OTO: NOTNLM; 2015/04/2
Place of Publication
Netherlands
ISSN/ISBN
1873-3573; 0039-9140
Accession Number
PMID: 26452919
Language
eng
SubFile
Journal Article; Research Support, Non-U.S. Gov't; IM
DOI
10.1016/j.talanta.2015.07.064 [doi]
Output Language
Unknown(0)
PMID
26452919
Abstract
A novel titanium dioxide-nanosheets coating on a titanium wire (TiO2NS-Ti) was in situ fabricated by one-step electrochemical anodization in ethylene glycol with ammonium fluoride and followed by phenyl-functionalization for selective solid-phase microextraction (SPME). The fabricated TiO2NS coating exhibits higher specific surface area and more active sites, it also provides an ideal nanostructure and a robust substrate for subsequent surface modification. These characteristics were useful for efficient extraction. The SPME performance of phenyl-functionalized TiO2NS-Ti (ph-TiO2NS-Ti) fiber was evaluated by using ultraviolet filters, polychlorinated biphenyls and polycyclic aromatic hydrocarbons (PAHs) as model compounds coupled to high performance liquid chromatography with UV detection (HPLC-UV). It was found that the ph-TiO2NS-Ti fiber exhibited high extraction capability, good selectivity and rapid mass transfer for PAHs. The main parameters affecting extraction performance were investigated and optimized. Under optimized conditions, the proposed fiber showed good extraction efficiency comparable to those of commercial polydimethylsiloxane and polyacrylate fibers toward PAHs. The calibration graphs were linear over the range of 0.05-300 microg L(-1). The limits of detection of the proposed method were 0.008-0.043 microg L(-1) (S/N=3). Single fiber repeatability varied from 3.51% to 5.23% and fiber-to-fiber reproducibility ranged from 4.43% to 7.65% for the extraction of water spiked with 25 microg L(-1) each analyte (n=5). The established SPME-HPLC-UV method was successfully applied to selective concentration and sensitive determination of target PAHs from real environmental water samples with recoveries from 86.2% to 112% at the spiking level of 10 microg L(-1) and 50 microg L(-1). The relative standard deviations were below 9.45%. Furthermore, the ph-TiO2NS-Ti fiber can be fabricated in a reproducible manner, and has high stability and long service lifetime.
Descriptors
Links
Book Title
Database
Publisher
Elsevier B.V
Data Source
Authors
Guo,M., Song,W., Wang,T., Li,Y., Wang,X., Du,X.
Original/Translated Title
URL
Date of Electronic
20150726
PMCID
Editors
Determination of polycyclic aromatic hydrocarbons in water by a novel mesoporous-coated stainless steel wire microextraction combined with HPLC 2010 College of Chemistry and Chemical Engineering, Northwest Normal University, Key Laboratory of Eco-Environment-Related Polymer Materials Ministry of Education, Lanzhou, PR China. wxm98@163.com
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Journal of separation science
Periodical, Abbrev.
J.Sep.Sci.
Pub Date Free Form
Oct
Volume
33
Issue
20
Start Page
3239
Other Pages
3244
Notes
LR: 20131121; JID: 101088554; 0 (Polycyclic Hydrocarbons, Aromatic); 059QF0KO0R (Water); 12597-68-1 (Stainless Steel); ppublish
Place of Publication
Germany
ISSN/ISBN
1615-9314; 1615-9306
Accession Number
PMID: 20839236
Language
eng
SubFile
Journal Article; Research Support, Non-U.S. Gov't; IM
DOI
10.1002/jssc.201000287 [doi]
Output Language
Unknown(0)
PMID
20839236
Abstract
A novel mesoporous-coated stainless steel wire microextraction coupled with the HPLC procedure for quantification of four polycyclic aromatic hydrocarbons in water has been developed, based on the sorption of target analytes on a selectively adsorptive fiber and subsequent desorption of analytes directly into HPLC. Phenyl-functionalized mesoporous materials (Ph-SBA-15) were synthesized and coated on the surfaces of a stainless steel wire. Due to the high porosity and large surface area of the Ph-SBA-15, high extraction efficiency is expected. The influence of various parameters on polycyclic aromatic hydrocarbons extraction efficiency were thoroughly studied and optimized (such as the extraction temperature, the extraction time, the desorption time, the stirring rate and the ionic strength of samples). The results showed that each compound for the analysis of real water samples was tested under optimal conditions with the linearity ranging from 1.02x10(-3) to 200 mug/ L and the detection limits were found from 0.32 to 2.44 ng/ L, respectively. The RSD of the new method was smaller than 4.10%.
Descriptors
Chromatography, High Pressure Liquid/economics, Polycyclic Hydrocarbons, Aromatic/analysis, Stainless Steel/chemistry, Time Factors, Water/chemistry
Links
Book Title
Database
Publisher
Data Source
Authors
Wang,X. M., Du,X. Z., Rao,H. H., Lu,X. Q.
Original/Translated Title
URL
Date of Electronic
PMCID
Editors
Oxidized multiwalled carbon nanotubes as a novel solid-phase microextraction fiber for determination of phenols in aqueous samples 2007 College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China.
Source Type
Print(0)
Ref Type
Journal Article
Periodical, Full
Journal of chromatography.A
Periodical, Abbrev.
J.Chromatogr.A
Pub Date Free Form
21-Sep
Volume
1165
Issue
2-Jan
Start Page
10
Other Pages
17
Notes
LR: 20131121; JID: 9318488; 0 (Nanotubes, Carbon); 0 (Phenols); 059QF0KO0R (Water); 2007/05/10 [received]; 2007/07/07 [revised]; 2007/07/10 [accepted]; 2007/07/31 [aheadofprint]; ppublish
Place of Publication
Netherlands
ISSN/ISBN
0021-9673; 0021-9673
Accession Number
PMID: 17707386
Language
eng
SubFile
Journal Article; Research Support, Non-U.S. Gov't; IM
DOI
S0021-9673(07)01251-4 [pii]
Output Language
Unknown(0)
PMID
17707386
Abstract
A simple and environmentally friendly method for determination of seven phenols using solid-phase microextraction (SPME) coupled to high-performance liquid chromatography (HPLC) has been developed. Several materials were used as stationary phase of SPME fibers and an oxidized multiwalled carbon nanotubes material was found to be effective in carrying out simultaneous extraction of phenols in aqueous samples. Compared with the widely used commercially available SPME fibers, this proposed fiber had much lower cost, longer lifetime (over 150 times), shorter analysis time (30 min of extraction and 3 min of desorption time) and comparable or superior extraction efficiency for the investigated analytes. The extraction and desorption conditions were evaluated and the calibration curves of seven phenols were linear (R(2)> or =0.9908) in the range from 10.2 to 1585 ng mL(-1). The limits of detection at a signal-to-noise (S/N) ratio of 3 were 0.25-3.67 ng mL(-1), and the limits of quantification calculated at S/N=10 were 0.83-12.25 ng mL(-1) for these compounds. The possibility of applying the proposed method to environmental water samples analysis was validated.
Descriptors
Chromatography, High Pressure Liquid/methods, Nanotubes, Carbon/ultrastructure, Oxidation-Reduction, Phenols/isolation & purification, Reproducibility of Results, Solid Phase Microextraction/methods, Water/chemistry
Links
Book Title
Database
Publisher
Data Source
Authors
Liu,X., Ji,Y., Zhang,Y., Zhang,H., Liu,M.
Original/Translated Title
URL
Date of Electronic
20070731
PMCID
Editors