Journal Article

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Acta crystallographica.Section E, Structure reports online

Acta Crystallogr.Sect.E.Struct.Rep.Online

1-Dec

68

Pt 12

o3371

LR: 20130418; JID: 101089178; OID: NLM: PMC3588967; 2012/11/10 [received]; 2012/11/11 [accepted]; 2012/11/17 [epublish]; ppublish

United States

1600-5368; 1600-5368

PMID: 23476203

eng

Journal Article

10.1107/S1600536812046533 [doi]

Unknown(0)

23476203

In the title mol-ecular salt, C12H22N5(+).Cl(-), the cation is protonated at the dimethyl-substituted tertiary N atom. The piperidine ring adopts a chair conformation with the exocyclic N-C bond in an equatorial orientation. The dihedral angle between the piperidine ring (all atoms) and the pyrimidine ring is 14.00 (1) degrees . In the crystal, the ions are connected by N-Hcdots, three dots, centeredN hydrogen bonds, forming inversion dimers, which are further connected by N-Hcdots, three dots, centeredCl hydrogen bonds. Aromatic pi-pi stacking inter-actions [centroid-centroid separation = 3.4790 (9) A] are also observed in the structure.

Sreenivasa,S., Manojkumar,K.E., Suchetan,P.A., Srinivasan,T., Palakshamurthy,B.S., Velmurgan,D.

Department of Studies and Research in Chemistry, Tumkur University, Tumkur, Karnataka 572 103, India.

20121117

PMC3588967

http://vp9py7xf3h.search.serialssolutions.com/?charset=utf-8&pmid=23476203

2012